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X-ray crystal structures of 10π- and 14π-electron pyrido-annelated N-heterocyclic carbenes

✍ Scribed by Nonnenmacher, Michael; Kunz, Doris; Rominger, Frank; Oeser, Thomas


Book ID
120610517
Publisher
Royal Society of Chemistry
Year
2006
Tongue
English
Weight
413 KB
Volume
13
Category
Article
ISSN
1359-7345

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The reaction of transient 1,3-dithiole-2,4,5-trithioue 4 with acenaphthylene afforded the Diels-Alder adduct 5, which was dehydrogenated to yield 6; cross-coupling of 6 with 7 gave the tetrathiafulvalene (TIT) derivative 8, which was converted into the di(methylsulfanyl) analogue 10, the solution el