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Why Does an Equilibrium Constant Not Appear Constant?

โœ Scribed by Martin, R. Bruce

Book ID
120417994
Publisher
American Chemical Society
Year
1998
Tongue
English
Weight
68 KB
Volume
75
Category
Article
ISSN
0021-9584

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## Abstract Analytical expressions are derived for the analysis of the accuracy of NMR determinations of conformational equilibrium constants, __K__. The relative error, ฯƒ~K~/__K__, shows a nearly linear increase with __K__ for two commonly used modifications of the NMR approach to conformational a