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How does the accuracy of NMR conformational analysis depend on the equilibrium constant?

✍ Scribed by N. M. Sergeyev

Publisher
John Wiley and Sons
Year
1978
Tongue
English
Weight
244 KB
Volume
11
Category
Article
ISSN
0749-1581

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✦ Synopsis

Abstract

Analytical expressions are derived for the analysis of the accuracy of NMR determinations of conformational equilibrium constants, K. The relative error, σ~K~/K, shows a nearly linear increase with K for two commonly used modifications of the NMR approach to conformational analysis (based on measurements of integral intensities and averaged chemical shifts).

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