White Metallopolyynes for Optical Limiting/Transparency Trade-off Optimization
✍ Scribed by Gui-Jiang Zhou; Wai-Yeung Wong; Zhenyang Lin; Cheng Ye
- Book ID
- 101536739
- Publisher
- John Wiley and Sons
- Year
- 2006
- Tongue
- English
- Weight
- 142 KB
- Volume
- 118
- Category
- Article
- ISSN
- 0044-8249
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## Abstract A new series of symmetric and unsymmetric Pt(II) bis(acetylide) complexes of the type DC≡CPt(PBu~3~)~2~C≡CD (DPtD), AC≡CPt(PBu~3~)~2~C≡CA (APtA) and DC≡CPt(PBu~3~)~2~C≡CA (DPtA) (D, donor groups; A, acceptor groups) are synthesized, and show superior optical power limi
The development of symmetric and unsymmetric platinum(II) bis(acetylide)s as highly transparent optical limiters is described by Wong and co-workers. Their excited state character is governed by electronic structure, which signifi cantly affects their photophysical properties and optical power limit