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Optical Power Limiters: Symmetric Versus Unsymmetric Platinum(II) Bis(aryleneethynylene)s with Distinct Electronic Structures for Optical Power Limiting/Optical Transparency Trade-off Optimization (Adv. Mater. 8/2009)

✍ Scribed by Guijiang Zhou; Wai-Yeung Wong; Suk-Yue Poon; Cheng Ye; Zhenyang Lin


Book ID
101414994
Publisher
John Wiley and Sons
Year
2009
Tongue
English
Weight
230 KB
Volume
19
Category
Article
ISSN
1616-301X

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✦ Synopsis


The development of symmetric and unsymmetric platinum(II) bis(acetylide)s as highly transparent optical limiters is described by Wong and co-workers. Their excited state character is governed by electronic structure, which signifi cantly affects their photophysical properties and optical power limiting (OPL) behavior. The sound OPL responses and low OPL thresholds together with their excellent optical transparency render these materials very promising candidates for practical devices for the protection of human eyes and other delicate electro-optic sensors.


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Symmetric Versus Unsymmetric Platinum(II
✍ Guijiang Zhou; Wai-Yeung Wong; Suk-Yue Poon; Cheng Ye; Zhenyang Lin 📂 Article 📅 2009 🏛 John Wiley and Sons 🌐 English ⚖ 708 KB

## Abstract A new series of symmetric and unsymmetric Pt(II) bis(acetylide) complexes of the type DC≡CPt(PBu~3~)~2~C≡CD (DPtD), AC≡CPt(PBu~3~)~2~C≡CA (APtA) and DC≡CPt(PBu~3~)~2~C≡CA (DPtA) (D, donor groups; A, acceptor groups) are synthesized, and show superior optical power limi