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What Controls the Reactivity of 1,3-Dipolar Cycloadditions?

✍ Scribed by Bernd Engels; Manfred Christl


Publisher
John Wiley and Sons
Year
2009
Tongue
English
Weight
230 KB
Volume
48
Category
Article
ISSN
0044-8249

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## Abstract Azomethine ylides generated from 5‐(alkoxycarbonylmethyl)phenanthridinium cations were studied in 1,3‐dipolar cycloadditions with dimethyl maleate and dimethyl fumarate as dipolarophiles. The cycloadducts with the pyrrolidino[1,2‐f]phenanthridine skeleton easily underwent dehydrogenatio