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Substituent Effects in 1,3-Dipolar Cycloadditions of Phenyl Azide

โœ Scribed by Priv.-Doz. Dr. Reiner Sustmann; Dipl.-Chem. Heinrich Trill


Publisher
John Wiley and Sons
Year
1972
Tongue
English
Weight
311 KB
Volume
11
Category
Article
ISSN
0044-8249

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โœ M. IHARA; Y. TANAKA; N. TAKAHASHI; Y. TOKUNAGA; K. FUKUMOTO ๐Ÿ“‚ Article ๐Ÿ“… 2010 ๐Ÿ› John Wiley and Sons โš– 33 KB ๐Ÿ‘ 1 views

Influence of a 2-Fluoro Substituent on Diastereoselectivity in the 1,3-Dipolar Cycloadditions of Nitrones. -2-Fluoro nitrones, e.g. (IIIa)-(IIIc), show reverse diastereoselectivity in the title reaction compared with 2-hydro nitrones such as (IIId)-(IIIf). It is noteworthy that no appropriate catal