Wet oxidation of acetic acid by H2O2 catalyzed by transition metal-exchanged NaY zeolites

✍ Scribed by F. Larachi; S. Lévesque; A. Sayari

• Publisher: Wiley (John Wiley & Sons)
• Year: 1998
• Tongue: English
• Weight: 166 KB
• Volume: 73
• Category: Article
• ISSN: 0268-2575
• DOI: 10.1002/(sici)1097-4660(1998100)73:2<127::aid-jctb941>3.0.co;2-t

✦ Synopsis

During the wet oxidation of contaminated wastewaters, the destruction of low molecular weight carboxylic acid intermediates such as acetic, glyoxalic, and oxalic acids is often the rate-controlling step. Oxidation of acetic acid, a very recalcitrant intermediate, requires compelling treatment severity. Heterogeneous catalytic wet oxidation of model acetic acid aqueous solutions was conducted under mild conditions (below the normal boiling point of water) using hydrogen peroxide over various transition metal-exchanged NaY zeolites. Treatment of Cu2ÈNaY with oxalic acid [OA] led to a catalyst, Cu2ÈNaY [OA], with sig-niÐcantly improved properties in terms of total organic carbon (TOC) removal efficiency and catalyst stability against leaching. This catalyst outperformed homogeneous Cu2by a factor of 2È2É5 times. Continuous feeding of H 2 O 2 reduced its undesirable decomposition. Improvement of the TOC-degradation performance by Cu2ÈNaY [OA] was tentatively attributed to the removal of sodium and possibly aluminium in the zeolite. 1998