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Weak Ferromagnetism and Dynamic Magnetic Behavior in a Single End-to-End Azide-Bridged Nickel(II) Chain

✍ Scribed by X.-T. Liu; X.-Y. Wang; W.-X. Zhang; P. Cui; S. Gao

Publisher: John Wiley and Sons
Year: 2006
Tongue: English
Weight: 518 KB
Volume: 18
Category: Article
ISSN: 0935-9648
DOI: 10.1002/adma.200600253

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## Abstract A new end‐to‐end azido double‐bridged copper(II) complex [Cu~2~L~2~(N~3~)~2~] (1) was synthesized and characterized (L=1,1,1‐trifluoro‐7‐(dimethylamino)‐4‐methyl‐5‐aza‐3‐hepten‐2‐onato). Despite the rather long CuCu distance (5.105(1) Å), the magnetic interaction is ferromagnetic with