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Three Novel End-to-End Single Azido-Bridged Ferromagnetic Copper(II) Chains: Synthesis, Crystal Structure, and Magnetic Behavior

✍ Scribed by Partha Sarathi Mukherjee; Tapas Kumar Maji; Albert Escuer; Ramon Vicente; Joan Ribas; Georgina Rosair; Franz A. Mautner; Nirmalendu Ray Chaudhuri

Publisher: John Wiley and Sons
Year: 2002
Tongue: English
Weight: 316 KB
Volume: 2002
Category: Article
ISSN: 1434-1948
DOI: 10.1002/1099-0682(200203)2002:4<943::aid-ejic943>3.0.co;2-m

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## Abstract A new end‐to‐end azido double‐bridged copper(II) complex [Cu~2~L~2~(N~3~)~2~] (1) was synthesized and characterized (L=1,1,1‐trifluoro‐7‐(dimethylamino)‐4‐methyl‐5‐aza‐3‐hepten‐2‐onato). Despite the rather long CuCu distance (5.105(1) Å), the magnetic interaction is ferromagnetic with