Weak CH⋅⋅⋅F Bridges and Internal Dynamics in the CH3F⋅CHF3 Molecular Complex
✍ Scribed by Walther Caminati; Juan C. López; José L. Alonso; Jens-Uwe Grabow
- Publisher
- John Wiley and Sons
- Year
- 2005
- Tongue
- English
- Weight
- 582 KB
- Volume
- 44
- Category
- Article
- ISSN
- 0044-8249
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📜 SIMILAR VOLUMES
A variety of relative and absolute techniques have been used to measure the reactivity of fluorine atoms with a series of halogenated organic compounds and CO. The following rate constants were derived, in units of cm3 molecule-' s-l: CH3F, (3.7 2 0.8) X CH3C1, (3.3 2 0.71 X 10 -'I; CH3Br, (3.0 2 0.
## Abstract The intermolecular interaction energy curves of CH~3~OCH~3~CH~2~F~2~, CF~3~OCH~3~CH~2~F~2~, CF~3~OCF~3~CH~2~F~2~, CH~3~OCH~3~CHF~3~, CF~3~OCH~3~CHF~3~, and CF~3~OCF~3~CHF~3~ complexes were calculated by the MP2 level __ab initio__ molecular orbital method using the 6‐311G\*\* basi