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Wavelength-resolved fluorescence lifetimes of gas-phase ions: CO2+ and CS2+

✍ Scribed by R.C. Dunbar; David W. Turner


Publisher
Elsevier Science
Year
1981
Tongue
English
Weight
539 KB
Volume
57
Category
Article
ISSN
0301-0104

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The allenyl anionreacts readily in the gas phase with CS2and COS to form the thioketenylanion. The reactinninvolvesa cnmplexseriesof cyclizationand riryg-opening reactionsin whichthe centralcarbonofallene mri the carbonof the neutralreagentbecomeequivalent. Despitethe complexity,the reactionwith CSZ