The Gas-Phase Reactions of the Allenyl A
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Charles H. DePuy; Veronica M. Bierbaum; Marin S. Robinson; Gustavo E. Davico; Ro
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Article
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1997
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Elsevier Science
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French
β 828 KB
The allenyl anionreacts readily in the gas phase with CS2and COS to form the thioketenylanion. The reactinninvolvesa cnmplexseriesof cyclizationand riryg-opening reactionsin whichthe centralcarbonofallene mri the carbonof the neutralreagentbecomeequivalent. Despitethe complexity,the reactionwith CSZ