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Absolute infrared intensifies of CS2 fundamentals in gas and liquid phases. An interpretation of the bond moments of CO2 and CS2

โœ Scribed by Willis B. Person; Lyle C. Hall

Publisher
Elsevier Science
Year
1964
Weight
645 KB
Volume
20
Category
Article
ISSN
0371-1951

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Bond strengths of the gas-phase cluster
Bond strengths of the gas-phase cluster ions Xโˆ’ (CS2)n (X = F, Cl, Br and I)
โœ Kenzo Hiraoka; Susumu Fujimaki; Kazuo Aruga; Shinichi Yamabe ๐Ÿ“‚ Article ๐Ÿ“… 1993 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 467 KB

Thermodynamic quantities, AH:\_ ,,\* and AS:\_ ,,", for the clustering reactions, X-(CSI),\_,+CSz=X-(CS,),, X=F, Cl, Br and I, were measured with a pulsed electron-beam high-pressure mass spectrometer. A large binding energy, 35.0 kcal/mol, for F-...CS2 has been obtained, whereas those for other X-.