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Water soluble, zero-valent, platinum?, palladium?, and nickel?P(CH2OH)3 complexes:catalysts for the addition of PH3 to CH2O

โœ Scribed by Harrison, Karl N.; Hoye, Peter A. T.; Orpen, A. Guy; Pringle, Paul G.; Smith, Martin B.


Book ID
121268703
Publisher
The Royal Society of Chemistry
Year
1989
Tongue
English
Weight
212 KB
Volume
16
Category
Article
ISSN
0022-4936

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The reactions of water-soluble phosphanes P(CH,OH), (1) and Ph2PCH20H (2) with NaAuC14 in aqueous or alcoholic media, produced the water/alcoholic-soluble Au' complexes [Au(P(CH,OH),),]+ (3) and [Au(Ph2PCH20H):J+ (4) in near quantitative yields. The X-ray structures of 3 and 4, reported in this pape