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Water-Promoted Palladium-Catalysed Heck Cross-Coupling Reactions of Aryl Halides with Alkenes in TBAB

โœ Scribed by Tao, Li Ming (author);Li, Qiang Guo (author);Liu, Wen Qi (author);Zhou, Yun (author);Zhou, Ju Feng (author)

Book ID
118011369
Publisher
Science Reviews 2000 Ltd
Year
2011
Tongue
English
Weight
86 KB
Volume
35
Category
Article
ISSN
1747-5198

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โœ Florian Berthiol; Henri Doucet; Maurice Santelli ๐Ÿ“‚ Article ๐Ÿ“… 2003 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 115 KB

cis,cis,cis-1,2,3,4-Tetrakis(diphenylphosphinomethyl)cyclopentane/[PdCl(C 3 H 5 )] 2 system catalyses efficiently the Heck reaction of aryl halides with linear alkenes such as pent-1-ene, oct-1-ene or dec-1-ene. Selectivities up to 70% in favour of E-1-arylalk-1-ene isomers can be obtained. In the p