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Tetraphosphine/palladium catalysed Suzuki cross-coupling reactions of aryl halides with alkylboronic acids

✍ Scribed by Isabelle Kondolff; Henri Doucet; Maurice Santelli

Book ID
108282544
Publisher
Elsevier Science
Year
2004
Tongue
French
Weight
126 KB
Volume
60
Category
Article
ISSN
0040-4020

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Palladium/tetraphosphine catalyzed suzuk
Palladium/tetraphosphine catalyzed suzuki cross-coupling of heteroarylboronic acids with aryl halides
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## Abstract magnified image __cis__,__cis__,__cis__‐1,2,3,4‐Tetrakis(diphenylphosphinomethyl)cyclopentane/[PdCl(C~3~H~5~)]~2~ efficiently catalyses the Suzuki reaction of heteroarylboronic acids with aryl bromides and also the coupling of arylboronic acids with heteroaryl bromides. The coupling of

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Tetraphosphine/palladium-catalysed Suzuki cross-coupling with sterically hindered aryl bromides and arylboronic acids
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cis,cis,cis-1,2,3,4-Tetrakis(diphenylphosphinomethyl)cyclopentane/[PdCl(C 3 H 5 )] 2 system efficiently catalyses the Suzuki cross-coupling of sterically hindered substrates. Very high turnover numbers can be obtained for the coupling of sterically hindered aryl bromides with benzeneboronic acid or