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Wagner Rearrangement of α-dl-6-Dimethylamino-4, 4-Diphenyl-3-Heptanol (α-dl-Methadol)

✍ Scribed by May, Everette L.; Perrine, T. D.


Book ID
127046200
Publisher
American Chemical Society
Year
1953
Tongue
English
Weight
373 KB
Volume
18
Category
Article
ISSN
0022-3263

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The crystafs of a 4:l mixture of 6-(N-benzyl-N-iert-butoxycarbonyIamino)-2,3,6,7-tetradeoxy~ a-aberythroand -p-oL-threa-hept-2-enopyranos-4-ulose were monoclinic, space group I??,/c, with cell dimensions: a = 9.490(2), h = 21.516(S), c = 10.279(2) A, p = 115.31(l)", Z = 4. The ulose ring had a half-