Preparation of isobutyl 3,4-anhydro-2, 6-dideoxy-DL-α-lyxo-lyxo-hexopyranoside and its kinetic resolution with microsomal epoxide hydrolase

Preparation of methyl 3,6-dideoxy-α-d-xy

Preparation of methyl 3,6-dideoxy-α-d-xylo-hexopyranoside (methyl α-abequoside) and its α-l-lyxo isomer by reduction of epoxides with lithium triethylborohydride

✍ Hans H. Baer; David J. Astles 📂 Article 📅 1984 🏛 Elsevier Science 🌐 English ⚖ 329 KB

We have recently described' the reductive desulfonyloxylation of some secondary p-toluenesulfonates of glycosides by lithium triethylborohydride (Super Hydride@', LTBH), which afforded high yields of deoxy sugars. The glycosides used were 4,6-0-benzylidenated glycopyranoside 2-and 3-tosylates, and t