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VUV photoelectron emission spectroscopy of liquid systems

✍ Scribed by Lucille Chia; Ladislav Nemec; Paul Delahay

Publisher
Elsevier Science
Year
1975
Tongue
English
Weight
358 KB
Volume
32
Category
Article
ISSN
0009-2614

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✦ Synopsis

Fekibility and potential usefulness of 'studying photoelectron emissicn by p&e.liquids or soIutions in the vacuum ultraviolet range (5' 10 eV) tie demonstrated by_,means of relatjvely-simple equipment. Experimental resu!ts include: quantum yield spectral response curves for ferracyanide, iodide and bromide ions; energy diskibution curves for ferrocyanide. The ph6toionization spectrum of ferrocytide iksolution is determined and interpreted in terms of bound-continuum transitions and autoionizatibn of excited bound states. ','

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Photoelectron emission spectroscopy of l
Photoelectron emission spectroscopy of liquid water
✍ Paul Delahay; Kathrin Von Burg πŸ“‚ Article πŸ“… 1981 πŸ› Elsevier Science 🌐 English βš– 456 KB

The threshold energy Et = 10.06 eV (0.002 eV standard deviation) is determined for photoelectron emission by liquid water and is correiated with Et = 8.45 eV for OH-(aq). Free energy changes and standard reduction potentials are c&u-Iated for both emission processes. Reorganization free energies are