Fekibility and potential usefulness of 'studying photoelectron emissicn by p&e.liquids or soIutions in the vacuum ultraviolet range (5' 10 eV) tie demonstrated by\_,means of relatjvely-simple equipment. Experimental resu!ts include: quantum yield spectral response curves for ferracyanide, iodide and
โฆ LIBER โฆ
Photoelectron emission spectroscopy of liquid water
โ Scribed by Paul Delahay; Kathrin Von Burg
- Publisher
- Elsevier Science
- Year
- 1981
- Tongue
- English
- Weight
- 456 KB
- Volume
- 83
- Category
- Article
- ISSN
- 0009-2614
No coin nor oath required. For personal study only.
โฆ Synopsis
The threshold energy Et = 10.06 eV (0.002 eV standard deviation) is determined for photoelectron emission by liquid water and is correiated with Et = 8.45 eV for OH-(aq). Free energy changes and standard reduction potentials are c&u-Iated for both emission processes. Reorganization free energies are correlated to salvation free energies for HzO*(aq) and OH-(aq).
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