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VLPP gives rate constant for radical reaction


Book ID
127017461
Publisher
American Chemical Society
Year
1968
Tongue
English
Weight
307 KB
Volume
46
Category
Article
ISSN
0009-2347

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The very-low-pressure pyrolysis (VLPP) o
โœ G. David Mendenhall; David M. Golden; Sidney W. Benson ๐Ÿ“‚ Article ๐Ÿ“… 1975 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 527 KB

The pyrolysis of n-propyl nitrate and tert-butyl nitrite at very low pressures (VLPP technique) is reported. For the reaction n-PrON02 A nPrO + NO2 the high-pressure rate expression at 300"K, log k, (sec-l) = 16.5 -40.0 kcal/mole/2.3 RT, is derived. The reaction tert-BuONO -% tert-BuO + N O was stud