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Visual Isotope Effects: Demonstrating the Primary Kinetic Isotope Effect in the Chromium(VI) Oxidation of 2-Propanol- d 8 and Methanol- d 4

✍ Scribed by Iskenderian-Epps, Wendy S.; Soltis, Chloe; O’Leary, Daniel J.

Book ID
120356015
Publisher
American Chemical Society
Year
2013
Tongue
English
Weight
238 KB
Volume
90
Category
Article
ISSN
0021-9584

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## Abstract The kinetic isotope effects in the reaction of methane (CH~4~) with Cl atoms are studied in a relative rate experiment at 298 ± 2 K and 1013 ± 10 mbar. The reaction rates of ^13^CH~4~, ^12^CH~3~D, ^12^CH~2~D~2~, ^12^CHD~3~, and ^12^CD~4~ with Cl radicals are measured relative to ^12^CH~