A non-destructive mild oxidation method of removing some impurities from as-grown carbon nanotubes (CNTs), including single-wall carbon nanotubes (SWNTs) and multi-wall carbon nanotubes (MWNTs), by H 2 O 2 oxidation and HCl treatment, has been investigated, and somewhat pure carbon nanotubes have be
Visible cathodoluminescence from carbon nanotubes: the role of impurities
✍ Scribed by Barberio, M. ;Barone, P. ;Bonanno, A. ;Camarca, M. ;Oliva, A. ;Pingitore, V. ;Xu, F.
- Publisher
- John Wiley and Sons
- Year
- 2008
- Tongue
- English
- Weight
- 336 KB
- Volume
- 205
- Category
- Article
- ISSN
- 0031-8965
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✦ Synopsis
Abstract
Luminescence spectra obtained by electron bombardment (cathodoluminescence, CL) on bundles of pristine single walled (SWCNT) and multi walled carbon nanotubes (MWCNT) show several common peaks at 1.76, 1.94, 2.06, and 2.22 eV which disappear after heating the samples up to 1300 K. We show that these transitions are extrinsic to nanotubes and originate from nickel oxide impurities, residual catalyst material used in the growth processes. Our conclusions are confirmed by X‐ray photoelectron spectroscopy (XPS) and energy dispersed X‐ray analysis measurements. (© 2008 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)
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