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Viscosities of aqueous tert-butyl alcohol solutions

✍ Scribed by Velo, Enrique; Puigjaner, Luis; Recasens, Francisco

Book ID
127395367
Publisher
American Chemical Society
Year
1991
Tongue
English
Weight
324 KB
Volume
36
Category
Article
ISSN
0021-9568

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Di-tert-butyl nitroxide (DTBN) decomposes in aqueous solutions producing 2-methyl-2-nitroso propane (MNP) and tert-butanol. The process is acid catalyzed, it is of second order in DTBN, and takes place with a rate constant of (1.0 2 0.1) M-\* s-'. The reaction is also catalyzed by the anionic surfac