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Influence of Urea on tert -Butyl Alcohol Aggregation in Aqueous Solutions

✍ Scribed by Paul, Sandip; Patey, G. N.

Book ID
118745875
Publisher
American Chemical Society
Year
2012
Tongue
English
Weight
510 KB
Volume
116
Category
Article
ISSN
0022-3654

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Di-tert-butyl nitroxide (DTBN) decomposes in aqueous solutions producing 2-methyl-2-nitroso propane (MNP) and tert-butanol. The process is acid catalyzed, it is of second order in DTBN, and takes place with a rate constant of (1.0 2 0.1) M-\* s-'. The reaction is also catalyzed by the anionic surfac