Vinylsilanes as substrates for the synthesis of sulfines
β Scribed by M. van der Leij; B. Zwanenburg
- Book ID
- 108384641
- Publisher
- Elsevier Science
- Year
- 1978
- Tongue
- French
- Weight
- 255 KB
- Volume
- 19
- Category
- Article
- ISSN
- 0040-4039
No coin nor oath required. For personal study only.
π SIMILAR VOLUMES
## Abstract Heteroconjugate addition of various alkyllithium reagents to Ξ±βsilylallenephosphonates 3b,c has been accomplished in high yields. The formation of thiopheneβ2βphosphonates 5, by heteroconjugate addition of organolithium to 3bc, followed by treatment with sulfur dioxide, proceeds in reas
Although much is known about the properties and chemistry of vinylsilanes,1~2 relatively little use has been made of them in organic synthesis.s We describe here the use of a vinylsilane as the precursor to the stereospecific synthesis of vinyl halides.