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Vinylpolymerisation mit reduzierenden Übergangsmetallverbindungen. 8. Polymerisation von Methylmethacrylat in Gegenwart von Molybdän(III)-chlorid und Oximen

✍ Scribed by N. Moszner; M. Hartmann


Publisher
John Wiley and Sons
Year
1985
Tongue
English
Weight
351 KB
Volume
36
Category
Article
ISSN
0323-7648

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Vinylpolymerisation mit reduzierenden Üb
✍ Moszner, Norbert ;Hartmann, Manfred 📂 Article 📅 1982 🏛 Wiley (John Wiley & Sons) ⚖ 324 KB

The polymerization of methyl methacrylate initiated by the redox system vanadium(lI1) chloride/carbon tetrachloride was studied. The rate of polymerization can be described by the equation R , = k . [VCI,]os5 . [CC14]o~5 . [MMA]'eo. The overall activation energies were estimated to be 7 4 3 kJ . mo