Vinylpolymerisation mit reduzierenden Üb
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Moszner, Norbert ;Hartmann, Manfred
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Article
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1982
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Wiley (John Wiley & Sons)
⚖ 324 KB
The polymerization of methyl methacrylate initiated by the redox system vanadium(lI1) chloride/carbon tetrachloride was studied. The rate of polymerization can be described by the equation R , = k . [VCI,]os5 . [CC14]o~5 . [MMA]'eo. The overall activation energies were estimated to be 7 4 3 kJ . mo