Vinylic cations from solvolysis. XIV. Anisyl rearrangement in the acetolysis of β,β-dianisyl-α-phenylvinyl bromide

Vinylic cations from solvolysis. XVI. Hi

Vinylic cations from solvolysis. XVI. High kcis/ktrans reactivity ratio in the solvolysis of α-bromo-β-tert-butyl-p-methoxystyrenes

✍ Zvi Rappoport; Addy Pross; Yitzhak Apeloig 📂 Article 📅 1973 🏛 Elsevier Science 🌐 French ⚖ 185 KB

The introduction of two S-substituents into a vinylic system has a relatively small effect on the rate of SN1 solvolysis, 2 while with S-monomethyl a-activated vinyl halides k cis'ktrans values of 8.3 , ' and ~a. 9.5 , 4 vere found. The largest