✦ LIBER ✦
Vinylic cations from solvolysis. XVI. High kcis/ktrans reactivity ratio in the solvolysis of α-bromo-β-tert-butyl-p-methoxystyrenes
✍ Scribed by Zvi Rappoport; Addy Pross; Yitzhak Apeloig
- Publisher
- Elsevier Science
- Year
- 1973
- Tongue
- French
- Weight
- 185 KB
- Volume
- 14
- Category
- Article
- ISSN
- 0040-4039
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✦ Synopsis
The introduction of two S-substituents into a vinylic system has a relatively small effect on the rate of SN1 solvolysis, 2 while with S-monomethyl a-activated vinyl halides k cis'ktrans values of 8.3 , ' and ~a. 9.5 , 4 vere found. The largest