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Vinylation of Grignard reagents. Catalysis by iron

✍ Scribed by Tamura, Masuhiko; Kochi, Jay K.

Book ID
111985223
Publisher
American Chemical Society
Year
1971
Tongue
English
Weight
374 KB
Volume
93
Category
Article
ISSN
0002-7863

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Iron-catalysed arylation of heteroaryl h
Iron-catalysed arylation of heteroaryl halides by Grignard reagents
✍ JΓ©rΓ΄me Quintin; Xavier Franck; Reynald Hocquemiller; Bruno FigadΓ¨re πŸ“‚ Article πŸ“… 2002 πŸ› Elsevier Science 🌐 French βš– 103 KB

Cross-coupling reaction of phenylmagnesium bromide with heteroaryl halides, in the presence of a catalytic amount of iron salts, is reported. Yields are moderate to good, and it is worth noting that this reaction has been applied to non-activate heteroaryl halides.