Vinyl Oxocarbenium Ions in Intermolecular (4 + 3) Cycloaddition Reactions. -A general procedure for the application of acetals such as (I) in (4 + 3) cycloadditions is developed. The best Lewis acids are TiCl4 and SnCl4; mixtures of TiCl4 and Ti(OiPr)4 are also effective. -(HARMATA,
Vinyl Oxocarbenium Ions in Intermolecular [4 + 3] Cycloaddition Reactions
โ Scribed by Harmata, Michael; Jones, Darin E.
- Book ID
- 126236869
- Publisher
- American Chemical Society
- Year
- 1997
- Tongue
- English
- Weight
- 108 KB
- Volume
- 62
- Category
- Article
- ISSN
- 0022-3263
No coin nor oath required. For personal study only.
๐ SIMILAR VOLUMES
## Abstract For Abstract see ChemInform Abstract in Full Text.
The rhodium(I1) acetate catalyzed decomposition of diethyl 4-diazopent-2enedioate in the presence of furans results in the formation of products derived from a [3 + 41 cycloaddition. The [3 + 4] cycloaddition of ally1 cations with dienesls2 has become a very useful method for the synthesis of seven-
In the presence of the N-heterocyclic carbene gold catalyst (NHC-AuIPr, 7), propargyl esters 1a-f and 13 undergo a [4C + 3C] cycloaddition reaction with cyclopentadiene and furan under mild conditions. The evidence suggests the formation of the seven-membered ring occurs by a direct cycloaddition pr