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ChemInform Abstract: Vinyl Oxocarbenium Ions in Intermolecular (4 + 3) Cycloaddition Reactions.

✍ Scribed by M. HARMATA; D. E. JONES

Publisher: John Wiley and Sons
Year: 2010
Weight: 27 KB
Volume: 28
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.199728052

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✦ Synopsis

Vinyl Oxocarbenium Ions in Intermolecular (4 + 3) Cycloaddition Reactions.

-A general procedure for the application of acetals such as (I) in (4 + 3) cycloadditions is developed. The best Lewis acids are TiCl4 and SnCl4; mixtures of TiCl4 and Ti(OiPr)4 are also effective. -(HARMATA,

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