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ChemInform Abstract: Vinyl Imidates in Cycloaddition Reactions: Synthesis of (.+-.)-Alloyohimbane.

โœ Scribed by Steven M. Sparks; Kenneth J. Shea


Publisher
John Wiley and Sons
Year
2000
Weight
33 KB
Volume
31
Category
Article
ISSN
0931-7597

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ChemInform Abstract: Vinyl Oxocarbenium
โœ M. HARMATA; D. E. JONES ๐Ÿ“‚ Article ๐Ÿ“… 2010 ๐Ÿ› John Wiley and Sons โš– 27 KB

Vinyl Oxocarbenium Ions in Intermolecular (4 + 3) Cycloaddition Reactions. -A general procedure for the application of acetals such as (I) in (4 + 3) cycloadditions is developed. The best Lewis acids are TiCl4 and SnCl4; mixtures of TiCl4 and Ti(OiPr)4 are also effective. -(HARMATA,