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Vinyl cations. 25. Solvolysis of cyclobuten-1-yl nonaflate. Evidence for a cyclic vinyl cation intermediate

โœ Scribed by Subramanian, L. R.; Hanack, M.


Book ID
127379321
Publisher
American Chemical Society
Year
1977
Tongue
English
Weight
276 KB
Volume
42
Category
Article
ISSN
0022-3263

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Vinyl cations, 22 a 1,2-hydride shift in
โœ Klaus-Peter Jรคckel; Michael Hanack ๐Ÿ“‚ Article ๐Ÿ“… 1975 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 137 KB

Recently we reprted about the first example of a 1.2-hydride shift durmg the generation of a vrnyl cation, a process well known for trlsubstituted car&mum ions 2) :Thls was obsermildurlng the solvolys~s of cls-and trans-3-cyclop~l-2-propen-2-yl-trifl~~~esulfo~~(tnflate)3! --The 1.2-hydride shLft was