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Vicinal Diamination of Alkenes under Rh-Catalysis

✍ Scribed by Olson, David E.; Su, Justin Y.; Roberts, D. Allen; Du Bois, J.


Book ID
126481631
Publisher
American Chemical Society
Year
2014
Tongue
English
Weight
520 KB
Volume
136
Category
Article
ISSN
0002-7863

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Metal-free catalytic vicinal diamination
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The development of an intramolecular vicinal diamination protocol using metal-free conditions is discussed. The reaction uses a bromide source to generate a Br(I) catalyst in situ from a benign terminal oxidant such as sodium chlorite. The reaction is of great scope and surpasses the transition-meta