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Vicarious C-amination of 1-methyl-4-nitropyrazole

✍ Scribed by V. A. Lopyrev; V. N. Elokhina; O. V. Krylova; A. S. Nakhmanovich; L. I. Larina; M. S. Sorokin; A. I. Vokin

Book ID
105513968
Publisher
Springer US
Year
1999
Tongue
English
Weight
114 KB
Volume
35
Category
Article
ISSN
0009-3122

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The primary radical anions of substrate in the reactions of vicarious nucleophilic substitution of hydrogen in 1-methyl-4-nitropyrazole with 1,1,1-trimethylhydrazinium iodide and 4-amino-1,2,4-triazole in t-BuOK-DMSO were observed and identified by EPR monitoring. The probable mechanism of the subst

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