Vicarious C-amination of 1-methyl-4-nitroimidazole
β Scribed by Olga V. Donskaya; Valentina N. Elokhina; Anatoly S. Nakhmanovich; Tamara I. Vakul'skaya; Lyudmila I. Larina; Aleksandr I. Vokin; Aleksandr I. Albanov; Valentin A. Lopyrev
- Book ID
- 104251791
- Publisher
- Elsevier Science
- Year
- 2002
- Tongue
- French
- Weight
- 104 KB
- Volume
- 43
- Category
- Article
- ISSN
- 0040-4039
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β¦ Synopsis
A one electron transfer process during the vicarious nucleophilic substitution C-amination of 1-methyl-4-nitroimidazole is detected by EPR-monitoring.
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## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a βFull Textβ option. The original article is trackable v
The primary radical anions of substrate in the reactions of vicarious nucleophilic substitution of hydrogen in 1-methyl-4-nitropyrazole with 1,1,1-trimethylhydrazinium iodide and 4-amino-1,2,4-triazole in t-BuOK-DMSO were observed and identified by EPR monitoring. The probable mechanism of the subst