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Vibronic intensities in the optical absorption spectra of Pr3+in Cs2NaPrxY1−xCl6: concentration and temperature dependence

✍ Scribed by T. Luxbacher; H. P. Fritzer; K. Gatterer; C. D. Flint

Book ID
110584364
Publisher
Springer US
Year
1995
Tongue
English
Weight
410 KB
Volume
62
Category
Article
ISSN
0021-9037

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Vibronic intensities in the optical abso
Vibronic intensities in the optical absorption spectra of Pr3+ in Cs2NaPrxY1−xCl6: concentration and temperature dependence
✍ Thomas Luxbacher; Harald P. Fritzer; Colin D. Flint 📂 Article 📅 1995 🏛 Elsevier Science 🌐 English ⚖ 341 KB

The 3H4~3P o transition in the absorption spectra of Pr 3+ in the hexachloroelpasolites Cs2NaPrxY~\_xCl6 (X=0.1 to x= 1 ) have been measured from 300 to 10 K. The electronic spectra are dominated by electric-dipole allowed vibronic origins enabled by Herzberg-Teller coupling. The two odd parity vibr