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Vibronic excitons in crystalline anthracene

✍ Scribed by Roberto E. Lagos; Richard A. Friesner

Publisher
Elsevier Science
Year
1984
Tongue
English
Weight
53 KB
Volume
31-32
Category
Article
ISSN
0022-2313

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πŸ“œ SIMILAR VOLUMES

Triplet excitons as probes for structura
Triplet excitons as probes for structural imperfections in crystalline anthracene
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The phosphorescence and delayed fluorescence associated with triplet exciton trapping in crystalline anthracene have been used to demonstrate the physical nature of many of the traps and to determine their depth.

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Changes in spectral frequencies and intensities recorded at low temperatures (4 to 40 K), as well as measurements of prompt-fluorescence lifetimes, of annealed and deformed high-purity single crystals of anthracene reveal that traps l013ed nt ca. 300 cm-' and 1500 cm-' below the Sr level may be ascr

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The energy and intensity of esciton transitions with k parallel to the UJlO! direction have been cnlculoled using boson theory and intermolecular interactions obtained by resxling the lattice sums of Silbcy, Jortner and Rice. Compclrison with the reflecrion espcrimznts of Koch and Otto shows substmt