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Vibration—rotation hamiltonian for nonrigid triatomic molecules with diatomic rigid core

✍ Scribed by B.I. Zhilinskii; V.A. Istomin; N.F. Stepanov

Publisher: Elsevier Science
Year: 1978
Tongue: English
Weight: 721 KB
Volume: 31
Category: Article
ISSN: 0301-0104
DOI: 10.1016/0301-0104(78)85133-7

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The present paper reports the derivation of a new theoretical model describing the rotation and vibration of a triatomic molecule. The new method is based on the MORBID (Morse Oscillatory Rigid Bender Internal Dynamics) method (P. Jensen, J. Mol. Spectross: 128, 478-501 (1988): P. Jensen. J. (hcm. S

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A complete expression of the effective Hamiltonian, and of the generators of its transformation to the reduced form, is considered as a Taylor series in dynamic variables for the \(E\)-type vibrational state of a rigid molecule with a point symmetry group \(C_{3 \mathrm{v}}\). The suggested reductio