Vibrationally resolved photoelectron spectroscopy of AlO− and AlO2−
✍ Scribed by Sunil R. Desai; Hongbin Wu; Lai-Sheng Wang
- Publisher
- Elsevier Science
- Year
- 1996
- Tongue
- English
- Weight
- 495 KB
- Volume
- 159
- Category
- Article
- ISSN
- 0168-1176
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The possible C,, CZv, and C,, structures of A102 corresponding to the two lowest electronic states which dissociate into the neutral Al('P) and 02(3Xg-) fragments have been investigated at the ab initio selfconsistent field (SCF) and CI levels using nonempirical pseudopotentials. The most stable str
Several isomolecular gaseous eo\_uilibria involving A10 and Ala0 were studied by mass spectrometry, and the resuIts were used :o derive the dissociation energies of the two molecular species. Good internal agreement was obtained among the various experiments, leading to DE (AIO) = 118.6 +-2.5 kcal a