Vibrational study of aspartic acid and glutamic acid dipeptides
✍ Scribed by J.T.López Navarrete; V. Hernández; F.J. Ramírez
- Book ID
- 107807275
- Publisher
- Elsevier Science
- Year
- 1995
- Tongue
- English
- Weight
- 285 KB
- Volume
- 348
- Category
- Article
- ISSN
- 0022-2860
No coin nor oath required. For personal study only.
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## Abstract A series of tris(__β__‐diketonato)lanthanides with Yb^3+^, Eu^3+^, and Nd^3+^ centers were characterized as luminescent sensing probes specific to glutamic acid, aspartic acid, and their dipeptides, which are important substrates involved in nervous systems, taste receptors, and other b
## Abstract Deprotonated dipeptides, on collisional activation, fragment by the characteristic process NH~2~CH(R^1^) CONHCH(R^2^)CO~2~^−^ → NH~2~^−^C(R^1^)CONHCH(R^2^)CO~2~H → ^−^NHCH(R^2^)CO~2~H + NH~2~C(R^1^)CO, when R^1^ and R^2^ = H or alkyl. However, when one of the constituent amino acids i