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Vibrational structure of n–π* transition of the UV absorption spectrum of acryloyl fluoride in the gas phase

✍ Scribed by Koroleva, Lidiya A.; Tyulin, Vladimir I.; Matveev, Vladimir K.; Pentin, Yuriy A.

Book ID
121713263
Publisher
Elsevier Science
Year
2014
Tongue
English
Weight
336 KB
Volume
122
Category
Article
ISSN
1386-1425

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The UV absorption spectrum of trimethylstlyl radical was observed at 256 nm for the first time by photolysing allyltrimethylsilane and hexamethyldisilane with an ArF excimer laser. A bimolecular rate constant for recombination of trimethylsilyl radical of (2.5 +0.5)X10-" molecule-' cm3 s-' was measu