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Vibrational Spectroscopy and Dynamics of Azide Ion in Ionic Liquid and Dimethyl Sulfoxide Water Mixtures †

✍ Scribed by Sando, Gerald M.; Dahl, Kevin; Owrutsky, Jeffrey C.


Book ID
120511951
Publisher
American Chemical Society
Year
2007
Tongue
English
Weight
188 KB
Volume
111
Category
Article
ISSN
0022-3654

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Molecular dynamics simulations of charged and neutral solutes in dimethyl sulfoxide (DMSO)-chloroform mixtures reveal pronounced nonideality in the solute diffusion with changes of composition of the mixtures. The diffusion coefficient of the anionic solute first decreases, passes through a minimum