Solvation structure and dynamics of potassium chloride ion pair in dimethyl sulfoxide–water mixtures
✍ Scribed by Siddique, Asrar A.; Dixit, Mayank K.; Tembe, Bhalachandra L.
- Book ID
- 121718548
- Publisher
- Elsevier Science
- Year
- 2013
- Tongue
- English
- Weight
- 843 KB
- Volume
- 188
- Category
- Article
- ISSN
- 0167-7322
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📜 SIMILAR VOLUMES
The rate constants for the replacement of water from the inner-coordination shell of C O ( N H ~) ~O H ~~+ , I, by dimethyl sulfoxide (DMSO) as DMSO gradually replaced water in the solvation shell of I were found to approach, and finally equal, the water-exchange rate constant of I in aqueous media
## Abstract __We study the structure and dynamics of hydrogen‐bonded complexes of H~2~O/D~2~O and dimethyl sulfoxide (DMSO) by infrared spectroscopy, NMR spectroscopy and ab initio calculations. We find that single water molecules occur in two configurations. For one half of the water monomers both