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Vibrational spectral assignment and enhanced resolution using magnetic vibrational circular dichroism

✍ Scribed by T.R. Devine; T.A. Keiderling


Book ID
108007385
Publisher
Elsevier Science
Year
1987
Tongue
English
Weight
291 KB
Volume
43
Category
Article
ISSN
1386-1425

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πŸ“œ SIMILAR VOLUMES


Magnetic vibrational circular dichroism
✍ Paul V. Croatto; Timothy A. Keiderling πŸ“‚ Article πŸ“… 1988 πŸ› Elsevier Science 🌐 English βš– 500 KB

Magnetic vibrational circular dichroism spectra of the title compounds are presented for the mid-IR region. The metalloporphytin E. modes have larger A terms than seen previously by an order of magnitude and are 2-3 times larger than in tetraphenylporphine. Comparison to the vibronic model is made.

Vibrational circular dichroism theory: f
✍ Laurence A Nafie; Teresa B Freedman πŸ“‚ Article πŸ“… 1987 πŸ› Elsevier Science 🌐 English βš– 740 KB

The theory of vibrational circular dichroism is formulated in terms of magnetic dipole atomic pofar tensors, an extension of infrared atomic polar tensors to magnetic dipole tmnsitions. Relations are provided to define a ~bmtion~ nuclear m~eti~ shielding tensor that describes electronic shiei~n# of

Rotationally Resolved Magnetic Vibration
✍ C.N. Tam; T.A. Keiderling πŸ“‚ Article πŸ“… 1993 πŸ› Elsevier Science 🌐 English βš– 541 KB

The magnetic vibrational circular dichroism (MVCD) spectra of \(\mathrm{HCl}\) and \(\mathrm{DCl}\) are presented. The average rotational \(g\)-value of \(\mathrm{H}^{35} \mathrm{Cl}\) in the first excited vibrational states was determined to be 0.451 and 0.449 for the \(P\) and \(R\) branches, resp