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Vibrational spectra of the heteropolyanion sodium octatungstotetraphosphate(12−) icosahydrate

✍ Scribed by Bini Lizbeth George; G. Aruldhas

Publisher
John Wiley and Sons
Year
1991
Tongue
English
Weight
232 KB
Volume
22
Category
Article
ISSN
0377-0486

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✦ Synopsis

Abstract

Based on group vibrations, a vibrational assignment is proposed for the (P~4~W~8~O~40~)^12−^ ion in Na~12~P~4~W~8~O~40~ · 20H~2~O. The WO~6~ octahedra and the PO~4~ tetrahedra are found to be distorted in the crystal. Multiple bands observed for the stretching and bending modes of water are due to different strongly hydrogen‐bonded water molecules.

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