The infrared and Raman spectra of were recorded and assigned on the basis of its structural charac-Nd 2 CuGe 2 O 8 teristics. The study was complemented with an analysis of the infrared spectra of other germanates of the same type containing di †erent lanthanide cations (Sm-Tm) and yttrium, and by c
Vibrational spectra of tetrametagermanates of the type Ln2CuGe4O12 (Ln=lanthanide or Y)
✍ Scribed by Enrique J. Baran; Claudia C. Wagner; Araceli E. Lavat; Concepción Cascales
- Publisher
- John Wiley and Sons
- Year
- 1997
- Tongue
- English
- Weight
- 251 KB
- Volume
- 28
- Category
- Article
- ISSN
- 0377-0486
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✦ Synopsis
The infrared and Raman spectra of a series of tetrametagermanates of composition (with Ln 2 CuGe 4 O 12 Ln = Eu-Lu and Y), containing a ring, were recorded and assigned on the basis of their structural Ge 4 O 12 8characteristics. Force constants and mean amplitudes of vibration for the terminal groups were also esti-GeO 2 mated.
📜 SIMILAR VOLUMES
The crystal structure of the known compounds Ln 5 Re 2 O 12 (Ln = Y, Gd, Dy±Lu) and the new isotypic terbium rhenate Tb 5 Re 2 O 12 was determined from X-ray data of a twinned crystal of Ho 5 Re 2 O 12 : B2/m, a = 1236.5(4) pm, b = 748.2(2) pm, c = 563.8(1) pm, c = 107.73(3)°, Z = 2, R = 0.034 for 3
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