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Vibrational spectra of molten and aqueous NaClO3 and KClO3

✍ Scribed by John B. Bates; Arvin S. Quist; G.E. Boyd

Publisher
Elsevier Science
Year
1972
Tongue
English
Weight
384 KB
Volume
16
Category
Article
ISSN
0009-2614

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✦ Synopsis

Rarnan spectra of molten h'aC103 snd KCfOJ a!td of aqueous solutions of these salts were measured over the frequency interval from 50 to 1200 cm -I. Infrared emission spectra of the molten chlorates and of chlorate-nitrate mixtures were recorded, and absorption spectra of aqueous sodium and potassium chiorate also were detcrmincd.

The +(e) and Y4Ce) modes of ClO; were split in the molten wit and aqueous solution spectra, and a singIe, weak band WIS observed between ca. 80 and 200 crnSf in the Raman spectra of molten NaC10~ and KCl0p.

πŸ“œ SIMILAR VOLUMES

Resonance raman and infrared spectra of
Resonance raman and infrared spectra of ClO3 radicals in electron irradiated NaClO3
✍ J.B. Bates; H.D. Stidham πŸ“‚ Article πŸ“… 1976 πŸ› Elsevier Science 🌐 English βš– 443 KB

Resonance Ram,In and infrared absorption spectra of CIO, radicals have been obscrvcd Irom measurements of crystal-hC NaCIO, irradiated at 77 K with 1.5 McV electrons. The C103 radicals occupy two sets of nonequivalent sites; radicals at one site are observed from rcsonancc scattering usins 6328 A cs