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Vibrational spectra and structure of the heptahydrodiborate ion, [B2H7]− in glycol ethers

✍ Scribed by Yoshiki Matsui; Robert C. Taylor

Publisher
Elsevier Science
Year
1989
Tongue
English
Weight
503 KB
Volume
45
Category
Article
ISSN
1386-1425

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✦ Synopsis

The i.r. and Raman spectra of the heptahydroborate ion, [B2H7]-, and its deuterated derivative, [B2D7]-, have been obtained in solution and assignments have been made of the observed bands. The data are interpreted as indicating a bent C, structure in solution. Normal coordinate calculations based on this model are presented.

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